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Fundamentals
inHaaronic
Atom Theory
.Fundamentals
inHaaronic
Atom Theory
This page is intentionally left blank
.Fundamentals
in hiaaronic
Atom Theory
A. Deloff
Soltan Institute for Nuclear Studies, Warsaw, Poland
V f e World Scientific
WB SL
New Jersey • London • Singapore • Hong Kong
Published by
World Scientific Publishing Co. Pte. Ltd.
5 Toh Tuck Link, Singapore 596224
USA office: Suite 202, 1060 Main Street, River Edge, NJ 07661
UK office: 57 Shelton Street, Covent Garden, London WC2H 9HE
For photocopying of material in this volume, please pay a copying fee through the Copyright
Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, USA. In this case permission to
photocopy is not required from the publisher.
ISBN 981-238-371-9
The purpose of this book is to describe some of the major advances in our
understanding of the fundamental properties of hadronic atoms and this
text is an outgrowth of our personal research in the field over the years.
The book has two parts: the first part is devoted to methods and the second
part contains applications and a brief survey of the experimental situation.
It has been assumed that the reader has a good knowledge of quantum
mechanics and has completed a first course on quantum field theory.
Since our primary intention was to present in a unified and integrated
manner the foundations of the macroscopic approach, we have stayed in
principle within the conventional picture of hadronic atoms based on a two-
body model Hamiltonian in which all strong interaction effects have been
simulated by an absorptive effective potential representing the complicated
interaction between the hadron and the nucleus. Thus, strictly speaking
we present here a quantum mechanical theory of the hadronic hydrogen
as in this case the two-body model happens to be exact. It is understood
that for heavier elements all many-body complications have been deferred
as they are supposed to be accounted for in the derivation of the effective
potential which in general can be expected to be an immensely complex
object. In this book, however, the problem of a microscopic derivation of
the effective potential has not been our primary concern. Instead, we adopt
a pragmatic philosophy that one has to explore first a simple macroscopic
prototype, especially that the phenomenological approach has had consid
erable successes in reproducing the hadronic atoms data, using effective
potentials of the simplest possible form. Nevertheless, it should be kept
in mind that some important many-body aspects of the problem might be
missed in result of this simplification.
The introduction of a complex nuclear potential into the description
vi Fundamentals in Hadronic Atom Theory
fundamental questions have been resolved. On the formal side, when the
nuclear potential is supplemented with the hadron-nucleus Coulomb inter
action, one has to cope with a quantum mechanical bound state problem
which is sufficiently complex to exhibit a highly non-trivial dynamical struc
ture. Consequently, our second objective was to assemble all the necessary
mathematical tools required to take on this complicated problem.
The actual nuclear potentials are known to be quite strong so that in
general one has to consider situations when they might be capable of sup
porting bound states of their own. In addition to the atomic spectrum
one would then expect to have nuclear bound states but since binding re
sults from a collaborative action of two potentials we prefer to call them
quasi-nuclear bound states: they become identical with the usual nuclear
bound states when the Coulomb interaction is turned-off. In contrast with
the atomic states, these quasi-nuclear bound states can be expected to
have much bigger binding, commeasurable with the energy scale typical for
strong interactions. On the other hand, it is well known that the atomic
level shifts could also be quite large and it is far from obvious how it might
be possible to distinguish the atomic states from the quasi-nuclear states.
In this book we show that this could be done by investigating pole trajecto
ries of the associated S-matrix. We believe that a clear-cut ramification of
the spectrum of a two-potential Hamiltonian is a new development of con
siderable importance. To amplify this point, suppose that we have located
a number of bound states in our two-potential problem, i.e we have located
a number of poles of the corresponding S-matrix in the k-plane. When the
depth of the nuclear potential is varied these poles will be moving in the
k-plane along certain trajectories and in the limit of vanishing depth the
poles corresponding to atomic states should resume unperturbed Coulomb
positions on the positive half of the imaginary axis. If this does not hap
pen, we have to do with a quasi-nuclear bound state. In the latter case,
when the nuclear attraction falls below certain minimal value, the bound
state pole travels towards the negative real axis and finally crosses to the
lower half of the k-plane. When this happens, the pole does not repre
sent a bound state anymore. Such behavior is typical for a bound state
pole generated by a short-ranged potential as has been well documented
in the literature. Although the quasi-nuclear bound states appear to have
similar features as the nuclear bound states but the presence of Coulomb
potential introduces one important difference. The central point here is
a remarkable saturation theorem, which to the best of our knowledge has
not been presented in the literature. This theorem states that given a real
viii Fundamentals in Hadronic Atom Theory
a separate survey.
It is our experience, that a heavy load of formalism is much easier
digested when a rapid access to a calculational stage has been appreciated.
We would like to believe, that this text will be useful for a practitioner in
the field looking for a complete box of tools so we have presented a variety
of different methods which could be immediately used to solve the complex
eigenvalue problem, testing numerically in each case their performance.
In addition to that, we have attempted to make the presentation as self-
contained as possible by covering the technical details and mathematical
techniques which are necessary to solve the problems discussed in the text
but with which the reader might be unfamiliar.
As mentioned above, in the second part of this book we make contact
with experiment. We thought that it would be convenient to have the
full hadronic atoms data base in one place. Therefore, we have taken the
trouble of tabulating the experimentally available strong interaction level
shifts and widths data. In our survey of the experimental material we
start with the simplest two-body systems like the two-meson atomic bound
states and the hadronic hydrogen atoms. Then, we turn to the much more
complicated three-body system of the hadronic deuterium. In this case a
microscopic treatment involves a Faddeev approach. Finally, we consider
all the remaining heavier atomic species for which the microscopic approach
becomes prohibitively difficult and therefore the analysis must be based on
the optical, or effective potential concept.
Although we have drawn freely from many different sources, we make no
pretense for completeness. Therefore, it is not unlikely that some important
subjects might have been omitted; after all, the selection of topics thought
to be fundamental obviously must be biased by personal prejudices of the
author.
The organization of this book is as follows. We begin with a quick
overview of the subject in the next chapter. Then, in Chapter 2, we ar
gue that with complex potentials the standard quantum mechanical scalar
product has to be modified by taking as the "bra" states the time reversed
eigenfunctions. They replace the usual complex conjugate eigenfunctions.
This extension allows to sustain orthogonality of the eigenfunctions but
the norm integral becomes a complex number which can take any value
and in particular may vanish. Chapter 3 contains a modern survey of
Coulomb wave functions whose arguments have been extended into the
complex domain. In Chapter 4 we discuss the Coulomb resolvent and the
different scattering operators. Chapter 5 summarizes the basic results of
Preface XI
Preface v
xiii
xiv Fundamentals in Hadronic Atom Theory
Bibliography 341
Index 349
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PARTI
Theoretical Background
This page is intentionally left blank
Chapter 1
Hadronic A t o m s — A n Overview
3
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CHAPTER VI
“But only yesterday,” said Mr. Lee, “Mr. Holmes learned that an
engine ordered by the commission to drive the British exhibit of
looms, of which there were thirty-three exhibitors, had been
condemned by the superintendent of machinery, Mr. Daniel Kinnear
Clark, and ordered out of the building.” He added that Mr. Holmes
went directly to Mr. Clark and applied for the place for my engine, the
bedplate of which, thanks to my precipitate action, had arrived and
was then on a truck, in England called a lurry, waiting to be
unloaded. In answer to Mr. Clark’s questions, Mr. Holmes had given
him his personal assurance that I would be there, and the rest of the
engine would be there in ample time, and it would be all that he
could possibly desire; and on that assurance he had got the place for
me.
I informed Mr. Lee that I also had something to tell him. I then
gave him the situation as already related. He looked very grave.
When I had finished he said: “Well, you are in a hole, sure enough;
but come, let us get some breakfast, and then we will see what
Easton & Amos can do for you.” After eating my first English mutton-
chop in a chop-house on the Strand, I accompanied Mr. Lee to their
works in the Borough, a long distance away, on the south or Surrey
side of the Thames, to reach which we crossed the Southwark
bridge.
None of the partners had yet reached the office. Very soon Mr.
James Easton arrived. He was a young man about my own age. Mr.
Lee introduced me and told my story. The instant he finished Mr.
Easton came across the room and grasped my hand most cordially.
“That’s the kind of pluck I like,” said he; “we will see you through, Mr.
Porter; we will build this engine for you, whatever else may have to
wait.” Directly he added: “We have a good deal of ‘red tape’ here, but
it won’t do in this case. There will be no time to lose. Come with me.”
He then took me through the shops and introduced me to every
foreman, telling them what he had undertaken to do, and gave each
of them the same instruction, as follows: “Mr. Porter will come
directly to you with his orders. Whatever he wants done, you are to
leave everything else so far as may be necessary, and do his work
as rapidly as possible.”
As I listened to these orders, I could hardly believe my senses or
keep back the tears. Coming on top of the devotion of Mr. Holmes
they nearly overcame me. The sudden relief from the pressure of
anxiety was almost too much. It seemed to me to beat all the fairy
stories I had ever heard. This whole-hearted cordiality of the first
Englishman I had met gave me a high idea of the people as a whole,
which, I am happy to say, a residence of over six years in England
served only to increase.
Returning to the office, we found Mr. Lee, who said, “Now, Mr.
Porter, I think Mr. Holmes would like to see you.” Getting the
necessary directions, in due time I found myself in the Exhibition
building on Cromwell Road and in the presence of Mr. Holmes, who
received me joyfully and led me at once to Mr. Clark’s office. As he
opened the door, Mr. Clark looked up from his desk and exclaimed,
“Good morning, Mr. Holmes; where is that engine?” “Well,” replied
Mr. Holmes, “here is Mr. Porter, and the engine is here or on the
way.” Mr. Clark asked me a number of questions about the engine,
and finally how many revolutions per minute it was intended to make.
I replied, “One hundred and fifty.” I thought it would take his breath
away. With an expression of the greatest amazement he exclaimed:
“What! a hundred and fifty! B—b—b—but, Mr. Porter, have you had
any experience with such a speed as that?” I told him my experience
with the little engine, which did not seem to satisfy him at all. Finally
he closed the matter, or supposed he had done so, by saying: “I
cannot allow such a speed here; I consider it dangerous.” I decided
instantly in my own mind not to throw away all that I had come for;
but I made no sign, but humbly asked what speed I might employ.
After a little consideration Mr. Clark replied: “One hundred and
twenty revolutions; that must not be exceeded.” This he considered a
great concession, the usual speed of stationary engines being from
fifty to sixty revolutions. I meekly acquiesced, then made my plans
for one hundred and fifty revolutions, and said nothing to anybody. I
had no idea of the gravity of my offence. It was the first time since I
was a child that I had been ordered to do or not to do anything, and I
had no conception of orders except as given by myself. If there was
any risk, I assumed it gaily, quite unconscious how such a daredevil
defiance of authority would appear to an Englishman. Mr. Clark
showed me my location, and gave me an order for my engine-bed to
be brought in immediately, and also other parts of the engine as
soon as they arrived. Trucks generally, I was told, had to wait in the
crowd about ten days for their turn to be unloaded.
Charles T. Porter
A.D. 1862
My London Exhibit, its Success, but what was the matter? Remarkable Sale of the
Engine.
But what was the matter? I will clear the way to answering this
question by relating the following incident: Six months later, with a
feeling of bitter disappointment, I contemplated my engine standing
alone where the place had been thronged with surging life. All the
other exhibits had been removed. This was left in stillness and
desolation, and I was making up my mind to the necessity of
shipping it home again, its exhibition to all appearance absolutely
fruitless—a failure, which I was utterly at a loss to comprehend,
when I had a call from Mr. James Easton, the same man who had
first welcomed me in England. His firm had perhaps the largest
exhibit in the Machinery Hall, of a waterfall supplied by a centrifugal
pump, and they had been frequent observers of the running of my
engine, which was quite near them. Mr. Easton bluntly asked me if I
thought my engine could be run 50 per cent. faster or at 225
revolutions per minute, because they had concluded that it could be,
and if I agreed with them they had a use for it themselves. Under the
circumstances I did not hesitate long about agreeing with them in
respect to both ability and price, and the sale was quickly concluded.
I noted an entire absence of any disposition to take an undue
advantage. Mr. Easton then told me that they were troubled with lack
of power every afternoon when the foundry blower was on, and had
long wanted to drive this blower independently. It needed to make
2025 revolutions per minute to give the blast they required, and they
had planned to drive it by a frictional gearing, nine to one, if my
engine could run at the necessary speed. So this most peculiar and
exceptional opportunity for its application, absolutely the only chance
for its sale that had appeared, and that at the very last moment,
prevented my returning home in disappointment. It is hardly
necessary to add that the engine proved completely successful. I
shall refer to it again.
The point of the incident is this: It established the fact, the
statement of which otherwise no one from the result would credit for
an instant, that, from the afternoon when the black and averted looks
of my loom exhibitors were changed to smiling congratulations down
to the close of the exhibition, the engine never once had a warm
bearing or was interrupted for a single moment. It was visited by
every engineer in England, and by a multitude of engine users, was
admired by every one, and won the entire confidence of all
observers in its speed, its regulation, and the perfection of its
diagrams; and yet in all that six months not a builder ever said a
word about building it, nor a user said a word about using it; and, as
week after week and month after month passed without a sign, I
became almost stupefied with astonishment and distress.
The explanation of this phenomenon was entirely simple, but I did
not know it, and there was no one to even hint it to me. I was among
a people whose fundamental ideas respecting steam-engines were
entirely different from those to which I had been accustomed, and I
knew nothing about them, and so could not address myself to them.
In the view of every Englishman a non-condensing engine was
rubbish. Those which were made were small, cheap affairs, mostly
for export. Neither a builder nor a user could regard a non-
condensing engine with the slightest interest.
Now I do not think that in my limited sphere of observation at
home I had ever seen a condensing stationary engine, except the
engine which pumped out the dry-dock at the Brooklyn Navy Yard. In
my mind condensing engines were associated with ships and
steamboats. At this exhibition also there were shown only non-
condensing engines. I did not think of the reason for this, that in this
part of London, far away from the Thames, no water could be had for
condensing purposes. I took it all as a matter of course, though I was
astonished at the queer lot of engines in the company of which I
found myself.
I was, of course, familiar with the development of the stationary
engine in England from the original type, in which the pressure of
steam below that of the atmosphere, and sometimes the pressure of
the atmosphere itself furnished the larger proportion of the power
exerted; but after all I carried with me my American ideas, which
were limited to non-condensing engines, and had no conception of
the gulf that separated my thoughts from those of the men about me.
My visitors always wound up with the same question, “How do you
drive your air-pump?” And in my innocence I uniformly replied, “The
engine is a non-condensing engine; it has no air-pump”; all
unconscious that every time I said that I was consigning the engine
to the rubbish heap. This reply was taken necessarily as a frank
admission that the high-speed engine was not adapted for
condensing. Of course, then, it had no interest for them. No doubt
many wondered why I should have troubled myself to show it there
at all. If I had thought more deeply I must have been struck by the
unvarying form of this question, always assuming the air-pump to be
a part of the engine, but which, of course, could not be used there,
and only inquiring how I worked it; and also by the fact that after
getting my answer the questioner soon departed, and I scarcely ever
saw the same visitor again. But I did not think deeply. Perhaps the
conditions of excitement were not favorable to reflection. All I thought
was that this same everlasting question, which at home I would
never have heard, was getting awfully monotonous. After a while this
annoying question came to be asked less and less frequently, and
also the engine attracted less and less attention. The engine had
failed in a vital respect, and I did not know it. That the fact of the
engine being non-condensing should have been an objection to it
never once entered my mind.
But I doubt if I could have bettered the matter, however alive to
this difficulty I might have been. I showed all I had yet accomplished.
In the minds of my visitors it no doubt appeared impossible to run an
air-pump successfully at such a speed; the water and air would be
churned into foam, and the valves would not close in time. This
objection I was not prepared to meet, for I had not thought on the
subject at all. Moreover, it could not have been met in any way
except by a practical demonstration. For that demonstration I had yet
to wait five years.
There were many things connected with this season which were
well worth remembering. One of these was the visit of the jury. It was
the only time I ever met Professor Rankine. There were two or three
Frenchmen on the jury, and they engaged in an animated discussion
of the question whether the steam could follow the piston at so great
a speed. I well remember the sharp exclamation with which
Professor Rankine put an end to this nonsense, when he had got
tired of it. “There is no limit to the speed at which steam will follow a
piston.”
One day I had a call from Mr. John Penn, Mr. William Fairbairn,
and Mr. Robert Napier, who came together on a visit of ceremony,
and presented me their cards. In return I presented to them the
cards of the engine. But their visit, like most others, closed with the
same inevitable question.
It was a delightful hour that Mr. F. W. Webb spent with me. He was
then assistant engineer of the London & Northwestern Railway under
Mr. Ramsbottom, afterwards Mr. Ramsbottom’s successor, and the
pioneer builder of compound-cylinder locomotives. He told me about
the new form of traveling-crane invented by Mr. Ramsbottom for the
shops at Crewe, which was driven by a flying-rope, a ³⁄₄-inch cotton
cord, and also of other inventions of Mr. Ramsbottom—among these
the automatic cylinder lubricator, in which the condensation of the
steam was so rapid, from the locomotive rushing through the
atmosphere, that only the water formed on the conical end of a bolt
was permitted to drop into the oil, other condensation running into a
circular trough and back through an external gooseneck pipe to the
steam-chest; and of their experiments to observe the rate of this
condensation. For this purpose they used soda-water bottles, which
they found capable of resisting a pressure of 200 pounds on the
square inch, and in which they could see the rapidity with which the
condensed water displaced the oil, thus leading to the above device
for limiting this action; also about the Ramsbottom piston rings,
which came to be, and still are, so largely used. These consist, as is
well known, of square wrought-iron rods, say ¹⁄₂ inch square, two for
each piston, sprung into grooves. What is not so generally known is
the way in which these rings were originated, which Mr. Webb then
described to me. As sold, these are not circular rings, but when
compressed in the cylinder they become truly circular and exert the
same pressure at every point. The original form was found for each
size in this way: A circular iron table was prepared, provided with a
large number of pulleys located radially and equidistant around its
edge. A ring having the section of the proposed rings, turned to the
size of the cylinder, and cut on one side, was laid on this table, and
cords were attached to it at equal distances passing over these
pulleys. Equal weights were hung on these cords, sufficient to
expand this ring to the extent desired. The form of the expanded ring
was then marked on the table, and to the lines thus obtained the
rings were then rolled. He told me also of the trough and scoop
invented by Mr. Ramsbottom, and now used the world over, for
refilling locomotive tanks while running at full speed. Being a
locomotive man, Mr. Webb did not ask about the way I drove my air-
pump.
Mr. Clark formed a scheme to indicate all the engines in the
exhibition, twenty-four in number, all English except mine, so far as I
remember, and employed my indicator for the purpose, the diagrams
being taken by myself. Only two exhibitors declined to have their
engines indicated. As I afterwards learned, most of the engines were
bought for use there, as exhibitors would not exhibit non-condensing
engines.
One of those who refused permission were Gwynne & Co., the
principal partner a nephew of my centrifugal-force friend of earlier
days. They exhibited a centrifugal pump supplying a waterfall. They
employed Mr. Zerah Colburn, then editor of The Engineer, to
investigate their pair of non-condensing engines and find out why
they used so much steam. He borrowed my indicator to make a
private test. Of course, I never saw the diagrams, but Mr. Colburn
informed me that by making some changes he had reduced the back
pressure to 7 pounds above the atmosphere, which he claimed to be
as good as could be expected. No material improvement in the
engines was to be observed, however.
Some of the diagrams taken on these tests exhibited almost
incredible faults. The only really good ones were from a pair of
engines made by Easton, Amos & Sons, also to drive a large
centrifugal pump, built for drainage purposes in Demerara, and
sustaining another waterfall. These showed the steam cut off sharply
at one third of the stroke by separately driven valves on the back of
the main slides. A mortifying feature of this work for myself was that
on testing the indicator Mr. Clark found that the area of the piston,
which was represented to be one quarter of a square inch, was really
considerably less than this, showing lamentable inaccuracy on the
part of the makers, as well as my own neglect to discover it. This
rendered the instrument valueless for measuring power, but it
showed the character of the diagrams all right.
The finest mechanical drawing I ever saw—or any one else, I think
—was shown in this exhibition. It was a drawing of the steamship
“Persia,” then the pride of the Cunard fleet, and was the only
mechanical drawing ever admitted to the walls of the National
Gallery, where it had appeared the year before. It represented side
and end elevations and plan, as well as longitudinal and cross-
sections, was painted and shaded in water-colors, and involved an
almost incredible amount of work. It was made by Mr. Kirkaldy, then
a draftsman in the employ of the Napiers, of Glasgow, the builders of
the vessel. I am tempted to refer to this, as it forms a prominent
datum point from which to measure the development of steam
navigation in the brief space of forty years. The vessel did not
possess a single feature, large or small, that now exists. It was of
only about 3000 tons burden. It was an iron ship built in the days of
the rapid transition from wood to steel. It was propelled by paddle-
wheels. These were driven by a pair of side-lever engines. The
engines had each a single cylinder. The steam pressure carried was
nominally 25 pounds above the atmosphere, but practically only from
15 to 20 pounds. Full pressure was not pretended to be maintained.
They had jet condensers. All forged work was of iron. The vessel
was steered by hand. The rigging, standing as well as running, was
of hemp. It was full bark-rigged.
Frederick E. Sickels
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